Daftari besheli department of physics, university of mazandaran, babolsar, iran email. This old technique of generating arc using electric current was first used to produce cnts by iijima in 1991. The tubes were produced using an arc discharge evaporation method similar to that used for the fullerene synthesis. Which are valuable for engineering, optics, electronics and nano technology 35, 36, and 37. Nano idea open access sensing and identification of carbon. In iijimas initial experiment 2, he used a dc arc discharge in argon consisting of a set of carbon electrodes running at 2000. Arc discharge process has scale up limitations and also sometimes requires the addition of a small amount of metal catalysts, which increases the yield of nanotubes. An arc between two electrodes can be initiated by ionization and glow discharge, when the current through the electrodes is increased. Iron, cobalt and nickel were used as catalysts, and sulfur was added as a promoter. The cylindrical carbon molecules feature high aspect ratios lengthtodiameter values typically above 10 3, with diameters from about 1 nanometer up to tens of nanometers and lengths up to millimeters.
The cnts, also known as tubular fullerenes, are cylindrical graphene. The most common method used to fabricate carbon nanotubes is electric arc discharge. They can be singlewalled swcnt with a diameter of less than 1 nanometer nm or multiwalled mwcnt, consisting of several concentrically interlinked nanotubes, with. Review article carbon nanotubes and its applications. Outline introduction synthesis overview arc discharge applications reference 3. However the first macroscopic production of carbon nanotubes was made in 1992 by two researchers at necs fundamental research laboratory. The cathode deposits are examined using scanning electron microscopy sem and scanning probe microscopy spm in afm mode to determine the microstructure and nanostructure of carbon nanotubes. Multiwalled carbon nano tubes are mainly found in the hard crust formed at the cathode, while nanohorned particles can be recovered from a cylindrical collector surrounding the discharge. Catalysts increases the quality and quantity made nanotubes. Carbon nanotubes have a range of electric, thermal, and structural properties that can change based on the physical design of the nanotube. The carbon rods act as electrodes which are kept at different potentials. The cylindrical carbon molecules feature high aspect ratios lengthtodiameter values typically above 103, with diameters from about 1 nanometer up to te. Jul 03, 2014 synthesis of cnt by arc discharge method 1.
Further material, raglike shaped and with an amorphous structure, can be collected in the reaction area. The sparking between the graphite electrodes, placed 12. Arc discharge decomposition generally, when a voltage is applied to two electrodes, an electrical potential is created which tends to move electrons from the positive pole to the negative. Preparation conditions for largescale synthesis of doublewalled carbon nanotubes dwcnts by using electric arc discharge were examined. Carbon nanotube, multiwalled asproduced cathode deposit, 7. Mar 07, 20 this was a part of my senior year high school science fair project.
Purity evaluation of asprepared singlewalled carbon. Iijima, 3 who was looking for new carbon structures, in the deposit formed on graphite cathode surfaces during the electric arc evaporation or discharge that is commonly employed to produce fullerene soot. This is a low cost technique as it does not require expensive apparatus 25, 26. Carbon nanotubes what they are, how they are made, what. The production of carbon nanotubes can be done by plasma based synthesis method or arc discharge evaporation method, laser ablation method, thermal synthesis process, chemical vapor deposition and. Complex structure of the carbon arc discharge for synthesis of nanotubes. Using arc discharge method, individual carbon nanotubes could be achieved in generally several hundred microns long. The purpose of this paper is to focus on the influence of electromagnetic field during the arc discharge carbon nanotubes synthesis. In the present work, the effect of doping on electronic properties in bulk purified and filled arc discharge singlewalled carbon nanotubes samples is studied for the first time by in situ raman spectroelectrochemical method.
Initially, the arc discharge method was used to produce carbon nanotubes. Masses of singlewalled carbon nanotubes swnts with a large mean diameter of about 1. It proposes modeling of electromagnetic field distribution to calculate forces in the area of arcing. The influence of starting carbon materials on the synthesis of carbon nanotubes cnts is investigated.
In quest to synthesize high quality carbon nanotubes in bulk, different routes have been proposed and established over the last two decades. Largescale production of singlewalled carbon nanotubes by the electric arc technique. They are pinning their hope on thermopower waves to produce electricity to be utilized in small electrical appliances or maybe in largescale applications too. Pdf synthesis of multiwall carbon nanotubes by electric. Synthesis of carbon nanotubes fb physik, fu berlin. The quality of the cnt obtained by electric arc depends on the quantity and quality of the catalyst, the geometry of the system, the pressure, the electric current of the. Synthesis of multiwall carbon nanotubes by electric arc discharge in liquid environments.
The major parameters are also evaluated in order to obtain highyield and highquality carbon nanotubes. The cathode was a graphite rod 16 mm diameter, 40 mm long. Y catalyst composition on the bulk scale synthesis of singlewalled carbon nanotubes swnts is studied using solution phase nearinfrared spectroscopy. The high temperature routes, such as the electric arc discharge technique. In our electric arc discharge apparatus 5, the arc is generated between two electrodes in a reactor under a helium atmosphere 660 mbar. During the arc discharge, that for the carbon nanotubes was firstly used by sumio. The structure of an ideal infinitely long singlewalled carbon nanotube is that of a regular hexagonal lattice drawn on an infinite cylindrical surface, whose vertices are the positions of the carbon atoms. Synthesis of highly crystalline carbon nanotubes by. An arc discharge is characterized by a lower voltage than a glow discharge and relies on thermionic emission of electrons from the electrodes supporting the arc. In this method electric arc burns between two graphite electrodes. The chamber consists of two electrodes which are mounted horizontally or vertically. Anode vaporize and decompose on the cathode forming deposit consisted on amorphous carbon, soot.
Comparisons are made between graphite rods and polycyclic aromatic hydrocarbons pahs as carbon sources in helium arc discharge. Synthesis of cnt by arc discharge method slideshare. Arc discharge is the oldest and among the best techniques to produce high quality carbon nanotubes. In our electric arc discharge apparatus 5, the arc is generated between two. Growth of carbon nanotubes cnt in electricarc discharge. Hydrogen storage in singlewalled carbon nanotubes at room. Nanotubes were observed in 1991 in the carbon soot of graphite electrodes during an arc discharge, by using a current of 100 amps, that was intended to produce fullerenes. The broad window of acceptable synthetic parameters found. Please use one of the following formats to cite this article in your essay, paper or report. We found that a wide range of catalyst concentrations 3. Arc discharge is the electrical breakdown of a gas to generate plasma. Preparation note electric arc discharge method other notes. Therefore, the current should be kept as low as possible.
This is what causes an electric flow of electrons or electric current through a wire or. During the arc discharge, that for the carbon nanotubes was firstly used by sumio iijima in 1991 1, two graphite rods are placed in an enclosure that is filled with some inert gas like helium or argon at low pressure between 50 and 700 mbar. On each of the tubes the carbonatom hexagons were arranged in a helical fashion about fig. Hydrogen and rare gases were used as buffer gases of the arc discharge. Fabrication, purification and characterization of carbon. Carbon nanotube, also called buckytube, nanoscale hollow tubes composed of carbon atoms. Growth conditions of doublewalled carbon nanotubes in arc. In the case of swnt synthesis by an arc discharge method, the incorporation of catalytic metal. What is shown in the video is the synthesis of carbon nanotubes via the arc discharge in water method. Synthesis of carbon nano tubes the mwcnts were initial known within the arc discharge methodology by lijma 38. Production methods for carbon nanotubes including arc. Electric arc discharge deposition eadd is used to produce cnt products.
Mar 27, 2014 applications of arc discharge method synthesis of metal nanoparticles. Filling of carbon nanotubes with metal is done by arc. Can we optimize arc discharge and laser ablation for well. The method involves the application of a magnetic field which enhances the yield of carbon nano tubes. The main process of growing carbon nanotubes in this method as same as arc discharge method also is exciting carbon atoms that are in contact with metallic catalyst particles. He was actually examining some sample of carbon clusters viz. On each of the tubes the carbon atom hexagons were arranged in a helical fashion about fig. When two or more concentric tubes are placed one into another, multiwalled carbon nanotube mwnt is formed. First, multiwalled boronnitride mwbn nanotubes were prepared by means of a modified electric arc discharge technique using boronnitride powder. The results of the outputs of all technological schemes are discussed on the basis of thermal analysis tga and dta, supported by tem and fullerenedissolving tests. Arc evaporation apparatus consists of two graphite electrodes under helium. Applications of arc discharge method synthesis of metal nanoparticles.
Synthesis of borondoped carbon nanotubes with dc electric. Arcdischarge, laser ablation, and chemical vapor deposition have been the three main methods used for carbon nanotube synthesis. Synthesis of highly crystalline carbon nanotubes by electric arc discharge and their field emission characteristics zain mehdi, taehun shin, jaeil lee and naesung lee dept. In this method, as shown in fig 2 nanotubes are produced through arc vaporization of two carbon rods placed end to end with a distance of 1mm in an environment of inert gas such as helium, argon at pressure between 50 to 700 mbar. Aug, 2014 this technique allows cnts to expand on different of materials and involves the chemical breakdown of a hydrocarbon on a substrate. Production methods for carbon nanotubes including arc discharge, laser, chemical vapor depsition and ball milling. An electric arc is an electrical breakdown of a gas which produces an ongoing plasma discharge, similar to the instant spark, resulting from a current flowing through normally nonconductive. Optimization of the carbon nanotubes synthesis in arc. Singlewalled carbon nanotube structure singlewalled carbon nanotubes can be formed in three different designs. Carbon nanotubes cnts are characterized as a graphene sheet rolledup to form a tube, for example a singlewalled tube swnt. Pdf synthesis of carbon nanotubes by arcdischarge method. It is well known that carbon nanotubes along with several other nanoparticles were.
Arc discharge method10 arc discharge method has been reported for producing carbon nanotubes. Electricarc discharge deposition was used to produce cnt products. Hirofumi takikawa, osamu kusano and nanotubes in arc. A major challenge to turn the potential of swcnts into customer applications is to. The design and electric scheme are discussed in details, as well as all technological features. Largescale production of singlewalled carbon nanotubes. An electric arc, or arc discharge, is an electrical breakdown of a gas that produces a prolonged electrical discharge. Growth of carbon nano tubes cnt in electricarc discharge in argon d. Electric arc discharge deposition was used to produce cnt products. The paper presents the influence of this field on the final product of the synthesis. Arcdischarge synthesis of carbon nanohorns and multiwalled. We present a joint experimental and theoretical study dedicated to analyze the properties of boronnitride bn nanotubes.
Synthesis of bcn nanomaterials by arc discharge using. Usage of carbon nanotubes and nano fibers in cement and. Preparation and characterization of multiwalled carbon nano tubes by liquid arcdischarge method 63 a transformer converts the moderate voltage and moderate current electricity from the utility mains into a high current and low voltage supply. This account presents our uptodate research on controlling the growth of carbon nanotubes by cvd approaches. Multiwalled carbon nanotube core surrounded by a fused carbon shell, the remainder being multilayer polygonal carbon nanoparticles and amorphous and graphitic carbon nanoparticles. One of the most popular method of carbon nanotubes synthesis is an electric arc discharge method. Largescale production of singlewalled carbon nanotubes by. The carbon nanotubes cnt have been produced under varying conditions of voltages and currents using different refluxing media. Modelling of fullerene production by the electric arc discharge method. Macroscopic quantities of multiwalled nanotubes were produced with an improved arc discharge method 15. Institute of solid state physics, russian academy of sciences, chernogolovka, moscow region, 142432 russia. A novel combination of two laser systems of different wavelengths for the laser ablation synthesis is presented.
A schematic of an arc discharge chamber is shown in fig. Two graphite electrodes are used to produce a dc electric arc discharge in. The raman spectra of mwnts are important because radial breathing modes with frequencies higher than 300 cm 1 and a new raman band near 1850 cm appear. This produces carbon nanotubes with decreased diameters and increased length. Recently, arc discharge in liquid media has been developed to synthesize several types of nano carbon structures such as. This work describes an electric arc installation based able to produce carbon nanostructures with. They found that carbon nanotubes discharge powerful waves of electricity under certain circumstances. The yield of dwcnts was sensitively dependent on the catalytic metal and the atmosphere gas, and it. The maximum current through an arc is limited only by the external circuit, not by the arc itself. In 1991, iijima reported the preparation of a new type of finite carbon structures consisting of needlelike tubes 3. Carbon nanotubes were so less in this sample that iijima himself said. Eaqub ali1, mohammed moinul islam2 and sharifah bee abd hamid1 abstract although many methods have been documented for carbon nanotube cnt synthesis, still, we notice many. Carbon nano tubes with all the above said properties will be used as additives to the structural materials.
Two graphite electrodes are used to produce a dc electric arcdischarge in inert gas atmosphere. International journal of engineering research and general. Carbon nanotubes cnts are cylindrical molecules that consist of rolledup sheets of singlelayer carbon atoms graphene. The current through a normally nonconductive medium such as air produces a plasma. A model of carbon nanotube synthesis in arc discharge plasmas. The laser ablation synthesis of carbon nanotubes is contrasted with the arc discharge method with respect to the synthesis product. This was a part of my senior year high school science fair project. Borondoped carbon nanotubes bdoped nts are predicted to behave as semiconductors over a large range of diameters and chiralities and might thus constitute a suitable class of materials for nanoelectronics technology. Experimental and theoretical studies of boron nitride.
Carbon nanotubes synthesis via arc discharge with a yttria. Mechanism of carbon nanostructure synthesis in arc plasma. This technique allows cnts to expand on different of materials and involves the chemical breakdown of a hydrocarbon on a substrate. Arcdischarge method the royal society of chemistry. A facile method is proposed to use a computer controlled arc discharge gap between graphite electrodes together with an yttrianickel catalyst to synthesize carbon nanotubes under an arh 2 gases mixture atmosphere by applying different dc currents and pressure. Synthesis of carbon nanotubes by arcdischarge method. Two graphite electrodes are used to produce a dc electric arc discharge in inert gas atmosphere. Arc evaporation synthesis, also known as electric arc discharge, has long been known as the best method for synthesizing fullerenes, and it also generates the highest quality carbon nanotubes. A method for the synthesis of carbon nanotubes where a directcurrent arc voltage is applied across two graphite electrodes immersed in an inert gas such as he. While arc discharge and laser ablation methods produce only tangled nanotubes mixed randomly with byproducts, we illustrate that siteselective cvd synthesis.
1058 295 913 859 1661 24 1480 1280 475 1546 1608 973 711 788 131 370 497 1533 840 180 130 1685 1564 682 753 38 265 720 1400 1371 1398 1032 553 1489 349 966 597 1032 592 949 1172 1354 972 431 422 1415